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Journal Articles Green Chemistry Year : 2021

Limonene dioxide as building blocks for 100% bio-based thermosets

Alice Mija
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Elodie Louisy
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Sara Lachegur
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Veronika Khodyrieva
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Philippe Martinaux
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Sandra Olivero
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Véronique Michelet
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Abstract

This study valorises the benign epoxidation of (R)-(+)-limonene to generate novel bio-resourced limonene dioxide monomers. Without additional steps of separation or functionalization, the racemic limonene dioxide was cured with glutaric and dimethylglutaric anhydrides leading to thermosets with high Tg (~98 °C) and good mechanical properties (σ = 27 MPa; ε = 3,5 %; E= 1150 MPa; E’ = 1650 MPa, Shore D = 78).
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Dates and versions

hal-03351462 , version 1 (22-09-2021)

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Alice Mija, Elodie Louisy, Sara Lachegur, Veronika Khodyrieva, Philippe Martinaux, et al.. Limonene dioxide as building blocks for 100% bio-based thermosets. Green Chemistry, 2021, ⟨10.1039/D1GC02732H⟩. ⟨hal-03351462⟩
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